Prevent Sending Duplicate record from MySQL and PHP

I have one table as ad_banner_queue which is i am using to generate the Queue based on weightage of ads. Ads are inserted into advertisement table. Queue will be generated if all existing ads which are in queue delivered to user.

Now the issue is how should i prevent to sending the duplicate ads in case of request came at same time and Rand() returned the same record?

Below is the Code:

<?php
/* To Get the random Ad */
public function getBanner($params) {
    /* Fetch the Random from table */
    $ads_queue = (new \yii\db\Query())
            ->select('ad_quque_id, banner_image, unique_code')
            ->from('ad_banner_queue')
            ->join('inner join', 'advertisement', 'ad_banner_queue.ad_id = advertisement.ad_id')
            ->where('is_sent=0')
            ->orderBy('RAND()')
            ->one();

    /* In case of queue is not there generate the new queue */
    if ($ads_queue === false) {
        $output = $this->generateAdQueue();
        //In case of something went wrong while generating the queue
        if ($output == false) {
            return array();
        }

        //Now fetch the record again
        $ads_queue = (new \yii\db\Query())
                ->select('ad_quque_id, banner_image, unique_code')
                ->from('ad_banner_queue')
                ->join('inner join', 'advertisement', 'ad_banner_queue.ad_id = advertisement.ad_id')
                ->where('is_sent=0')
                ->orderBy('RAND()')
                ->one();
    }

    /* Now, marked that one as is_sent */
    Yii::$app->db->createCommand()->update('ad_banner_queue', ['is_sent' => 1], 'ad_quque_id =:ad_quque_id', array(':ad_quque_id' => $ads_queue['ad_quque_id']))->execute();
    return $ads_queue;
}

/**
 * Below will Generate the Queue if not exist
 */
public function generateAdQueue() {
    /* First check thatt there is existing queue, if so don't generate it */
    $data_exist = (new \yii\db\Query())
            ->select('ad_quque_id')
            ->from('ad_banner_queue')
            ->where('is_sent=0')
            ->scalar();
    if ($data_exist === false) {
        /* Delete all other entries */
        (new \yii\db\Query())
                ->createCommand()
                ->delete('ad_banner_queue')
                ->execute();

        /* Fetch all banner */
        $ads = (new \yii\db\Query())
                ->select('ad_id, unique_code, ad_name, banner_image,ad_delivery_weightage')
                ->from('advertisement')
                ->where('status_id in (8)') //Means only fetch Approved ads
                ->all();
        if (!empty($ads)) {
            foreach ($ads as $ad) {
                /* Make entry as per that weightage, example, if weightage is 10 then make entry 10 times */
                $ins_fields = array();
                for ($i = 1; $i <= $ad['ad_delivery_weightage']; $i++) {
                    $ins_fields[] = array($ad['ad_id']);
                }
                Yii::$app->db->createCommand()->batchInsert('ad_banner_queue', ['ad_id'], $ins_fields)->execute();
            }
            return true;
        } else {
            return false;
        }
    } else {
        return false;
    }
}

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